Flow Structure when Filling a Channel with a Curable Liquid

Document Type : Research Paper

Authors

1 Faculty of Physics and Engineering, Tomsk State University, 36, Lenin Ave., Tomsk, 634050, Russia

2 Faculty of Physics and Engineering, Tomsk State University, 36, Lenin Ave., Tomsk, 634050, Russia‎

Abstract

The filling of a plane gap with a non-Newtonian fluid under non-isothermal conditions is considered by assuming viscous dissipation and curing reaction induced by the heat supplied through the walls of the gap. The rheology of the medium is described by the modified Cross-WLF model accounting for the effect of temperature, strain rate intensity, and the extent of a chemical reaction on the viscosity. The curing reaction kinetics is determined by the equation based on the n-th order reaction with self-acceleration. The problem is solved numerically using an original computational technique. The curable fluid flow structure is revealed to include three characteristic zones during the filling process: a fixed layer on the solid wall with a high degree of curing; a central “core” with an almost uniform distribution of characteristics; and a transition zone serving as a "lubricating" layer between two abovementioned zones. The structure is governed by heating of the fluid through the wall, since the heating affects the rheological characteristics of the medium and the rate of the cured layer formation. Analysis of the similarity criteria for the considered flow conditions shows that the fluid flows in a creeping regime (Re < 0.01); the temperature distribution is mainly affected by convective heat transfer (Pe > 100); the influence of dissipative heating and exothermic effect of the curing reaction is insignificant. The effect of curing on the mass distribution of the liquid portions entering through the inlet section is shown. The variation of the pressure distribution is analyzed at various flow conditions.

Keywords

Main Subjects

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[1] Mitsoulis, E., Fountain flow revisited: The effect of various fluid mechanics parameters, AIChE J., 56(2), 2010, 1147-1162.
[2] Mavridis, H., Hrymak, A.N., Vlachopoulos, J., Mathematical modeling of injection mold filling: A review, Adv. Polym. Technol., 6(4), 1986, 457-466.
[3] Coyle, D.J., Blake, J.W., Macosko, C.W., The kinematics of fountain flow in mold-filling, AIChE J., 33(7), 1987, 1168-1177.
[4] Borzenko, E.I., Ryltsev, I.A., Shrager, G.R., Kinematics of Bulkley-Herschel fluid flow with a free surface during the filling of a channel, Fluid Dyn., 52(5), 2017, 646-656.
[5] Borzenko, E.I., Ryltseva, K.E., Shrager, G.R., Free-surface flow of a viscoplastic fluid during the filling of a planar channel, J. Nonnewton. Fluid Mech., 2018, 254, 12-22.
[6] Borzenko, E.I., Shrager, G.R., Effect of viscous dissipation on temperature, viscosity, and flow parameters while filling a channel, Thermophys. Aeromechanics, 21(2), 2014, 211-221.
[7] Tomashevsky, V.T., Yakovlev, V.S., Coupled problems of mechanics and chemical physics in the technology for producing composite polymer materials, Mater. Phys. Mech., 8(1), 2009, 32-64.
[8] Malkin, A.Y., Kulichikhin, S.G., Rheokinetics of curing, Polymer Compositions Stabilizers/Curing, Springer-Verlag, 1991.
[9] Gillham, J.K., Formation and properties of thermosetting and high Tg polymeric materials, Polym. Eng. Sci., 26(20), 1986, 1429-1433.
[10] Urbaniak, M., Grudzinski, K., Time-temperature-transformation (TTT) cure diagram for EPY epoxy system, Polimery, 52(2), 2007, 117-126.
[11] Muc, A., Romanowicz, P., Chwał, M., Description of the Resin Curing Process - Formulation and Optimization, Polymers (Basel), 11(127), 2019, 1-22.
[12] Domínguez, J.C., Rheology and curing process of thermosets, Chapter 4, Thermosets. Elsevier, 2018.
[13] Bont, M., Barry, C., Johnston, S., A review of liquid silicone rubber injection molding: Process variables and process modeling, Polym. Eng. Sci., 61(2), 2021, 331-347.
[14] Wittemann, F., Maertens, R., Kärger, L., Henning, F., Injection molding simulation of short fiber reinforced thermosets with anisotropic and non-Newtonian flow behavior, Compos. Part A Appl. Sci. Manuf., 124(105476), 2019, 1-9.
[15] Wittemann, F., Maertens, R., Bernath, A., Hohberg, M., Kärger, L., Henning, F., Simulation of Reinforced Reactive Injection Molding with the Finite Volume Method, J. Compos. Sci., 2(5), 2018, 1-16.
[16] Tran, N.T., Gehde, M., Creating material data for thermoset injection molding simulation process, Polym. Test., 73, 2019, 284-292.
[17] Hong, Y.G., Lee, S., 3-D Modeling of Epoxy Reaction Molding Process for GIS Spacer, Polym. Korea, 45(6), 2021, 940-947.
[18] Teng, S-Y, Hwang, S-J., Simulations and experiments of three-dimensional paddle shift for IC packaging, Microelectron. Eng., 85(1), 2008, 115-125.
[19] Khor, C.Y., Abdullah, M.Z., Lau, C-S, Azid, I.A., Recent fluid–structure interaction modeling challenges in IC encapsulation – A review, Microelectron. Reliab., 54(8), 2014, 1511-1526.
[20] Lipanov, A.M., Alies, M.Yu., Konstantinov, Yu.N., Numerical simulation of creep flow for non-Newtonian fluids with free interface, Mat. Modelirovanie, 5(7), 1993, 3−9.
[21] Kamal, M.R., Sourour, S., Kinetics and thermal characterization of thermoset cure, Polym. Eng. Sci., 13(1), 1973, 59-64.
[22] Cross, M.M., Rheology of non-Newtonian fluids: A new flow equation for pseudoplastic systems, J. Colloid Sci., 20(5), 1965, 417-437.
[23] Williams, M.L., Landel, R.F., Ferry, J.D., The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids, J. Am. Chem. Soc., 77(14), 1955, 3701-3707.
[24] Castro, J.M., Macosko, C.W., Studies of mold filling and curing in the reaction injection molding process, AIChE J., 28(2), 1982, 250-260.
[25] Patankar, S V., Numerical Heat Transfer and Fluid Flow, Hemisphere Pub. Corp, 1980.
[26] Vasenin, I.M., Sidonskii, O.B., Shrager, G.R., Numerical solution of the problem on the movement of a viscous fluid with a free surface, Dokl. Akad. Nauk. SSSR, 217(2), 1974, 295-298.
[27] Yakutenok, V.A., Borzenko, E.I., Numerical simulation of viscous incompressible liquid with free interface using the SIMPLE method, Mat. Modelirovanie, 19(3), 2007, 52-58.
[28] Frigaard, I.A., Nouar, C., On the usage of viscosity regularisation methods for visco-plastic fluid flow computation, J. Nonnewton. Fluid Mech., 127(1), 2005, 1-26.
[29] Borzenko, E.I., Shrager, G.R., Flow of a Non-Newtonian Liquid with a Free Surface, J. Eng. Phys. Thermophys., 89(4), 2016, 902-910.